i cannot find a way to get my xfire to work after the game goes to the pvp.net client to screen shot everyones scores and the time it took, can anyone tell me how to fix this?

You cant.
Xfire in-game only works in-game. And since the pvp.net isnt in-game it wont work.

You can screen them with paint, but you wont be able to upload them to xfire then.

If you want you can make a little movie of it, using some thirth party program, you can upload it manually into xfire, if you really want it there so badly

:/ just want xfire to do it.

Its a problem inside xfire, therefor LoL can't really do anything about it.

Although if I find a way to make those screenys, Ill let you know.

As previously mentioned, Xfire only works ingame. Xfire works by waiting until the .exe is launched, then it "hooks" into the process and is able to do it's features. The launcher is not hooked in to, but if you wanted this feature I'd advise contacting Xfire team and asking for it.

why cant you make the Launcher connect to the xfire? i mean i tryd by changing the place where xfire loaded or w/e but didnt work.

xfire doesnt care as much about a single person compared to a whole community, if more people had this issue or wanted what i wanted i bet they would look into the matter.

Xfire hasn't been quite as much fun since MTV took over, they're more businessy and less community :-P But this isn't something Riot has any control over unfortunately, as far as the launcher is concerned.