Gambling and Card Tricks with Professor Fate. Best elective ever. 
Law 101 with Professor Kayle. One time her sword suddenly ignited on it's own and caught fire to the room and we had to evacuate the building. 
Mechanical Engineering with Professor Rumble. Pretty cool ****, but the last time a classmate even laid a finger on "Tristy" (thats what he calls his mech), he tazed them. And apparently, making any mention whatsoever of Professor Heimerdinger gets you kicked out of the class. ._.
Advanced Arcane Magic with Professor Xerath. A lot of students complain about how insanely friggin' hard it is, but i'm more worried about the punishments he dishes out...
Anthropomancy 101 with Professor Nasus. Quite possibly the sickest class i've ever taken...
Vocal Music with Professor Karthus. He looks likes he's never eaten a day in his life, but hey. The guy has a phenomenal voice.