King Rammus, sadly, is no longer available. Failing that, I'd probably pick Chrome Rammus over Ninja Rammus (TMNT!) as a close second. The other three, IMO, are just boring; "Freljord Rammus" and "Molten Rammus" are the obligatory ice/fire skins that seemingly every champion has. (I know that's not the case, but they're WAY too common)
Full Metal Rammus, IMO, is one of the over-rated ones, as are most of the all-too-popular "robot" skins. I'd also avoid it for reason that the store's indicated it's been in the top 5 item sales ever since it came out like a month ago, so you can count on a lot of others having it; and it's not all that amazing to make up for it. (contrast to, say, Arcade Sona, which I'd use if I played Sona in spite of its popularity)