I made another post but I'll move the part I made about this here...
1. Role selection - One thing that really ruins the low level games is the inability for people to consider the overall compilation of their team. In most games I notice this happens because of a complete lack of knowledge on what their characters are really doing for their team. Many of the games I enter have at least 2 AD carries on a team and some are just 5 bruisers who get poked to death. Another aspect of this that can ruin games is lane selection. One person calls top and locks in as Nasus, another selects a jungler, and then some (selfish and immature) player quickly locks in as Jax and says he's going top. The first 4 minutes of the game are then dedicated to the top lane players "V" - pinging each other to death until someone submits. Some times this can lead to Ashe / Jax up against a good Sona / Ezreal combo and the game plays out from there...
The solution, I feel, is obvious. In the champion selection screen have it set so that players can lock in their lane and have the option to call their role. Have a button next to champion portraits that turns into a drop box where you can select which lane you are going to. Other players then can only select the remaining positions. If someone chooses "Jungle" then the system will only allow for one character on top lane or bottom lane depending on which one already has two (or some other maths that I haven't thought of). Under the lane selection have another drop box that may or may not be exclusive (as in it wont prevent anyone else from doing anything) where they can display which role they would like to play. This would make everything perfectly clear to the team and also introduce new players to their roles and make them more aware.
Then I was also thinking what if they made a system that would let you set your rune/ mastery setup according to your champion/lane/ role selection. Then you wouldn't have to keep resetting it, it would all be automatic. You would decide this option while you were putting the pages together.