I did my typical analysis for a new character. I removed any value for Mp5 or Mana and looked at what AP items Shen would want, here's the ranked list:
Mejai's Soulstealer (20)
Guinsoo's Rageblade (8)
Mejai's Soulstealer (half)
Doran's ring
Rod of Ages (full)
Zhonya's Ring (100)
Abyssal Scepter
Zhonya's Ring (80)
Guinsoo's Rageblade
Blasting Wand
Amplifying Tome
Rylai's Scepter
Archangel's Staff (4k)
The Black Cleaver
Zhonya's Ring
Kage's Lucky Pick
Trinity Force
Rod of Ages (half)
Nashor's Tooth
Rod of Ages
Rylai's does help chase, I've tested it. Rageblade seems like a good choice since you'll be proc'ing and casting on 8 stacks often. If you're good and can protect the stacks, mejai's could be sick otherwise z-ring rounds out the AP items you'd want.
That third item doesn't seem very practical. I'd probably go with something else tanky instead. With some mpen, your overall DPS as well as burst damage would increase with a build like this. So, I'm thinking my tank items would be Soulfire cape(s).
edit: BTW, everything after blasting wand is a negative value item.