Just wanted to share an illustration of Caitlyn that I just finished. Being the ever-dependable Sheriff of Piltover, she sits above the city, keeping a watchful eye out for any trouble and/or Blitzcranks...
This one took forever, especially getting her gun and outfit right (and they're still not 100% accurate). Hopefully I can find the time to do a whole series of these in the near future, twas a good time.
For all my future artwork check out my http://tsuaii.deviantart.com, otherwise visit http://gravija-sunrise.deviantart.com for all my old stuff.
EDIT: By the way, I did this in Photoshop CS5 with a Wacom Intuos 2 tablet. Used refs for the face (based on Anne Hathaway, mmm) and for Cait's gun and outfit. Also, I did part of this on Livestream if you're interested in seeing the process (albeit late in production): http://livestre.am/SAz1
EDIT II: Thanks for such a huge response! There have been some requests for a wallpaper, so I put together a 1280x1024. Did my best to hide the messy strokes in the bottom half of the painting, hehe
EDIT III: Added the step-by-step process shots. Unfortunately the wide screen version of the scene no longer exists, as I cropped the image right before finishing it. Kinda wish I hadn't.
EDIT IV: I didn't make it into the Summoner's Showcase :c
EDIT V: Made it into the Summoner's Showcase!