I'll take a stab (personal opinions)
Tier 1 - god
Twitch
Shaco (Move to tier 2)
Master Yi (Move to teir 3 -- too easily shut down with blinds and stuns)
Tier 2 - Top
Teemo
Corki
Kayle (Move to tier 3 -- Bubble is nice, but kayle isn't top tier)
Rammus
Zilean (Move to tier 4 - Speed up slow down and revive are wonderful when they're cast on you, but they rarely change the outcome of battles.)
Alistar
Cho'Gath
Nunu
Annie
Veigar
Fiddlesticks
Katarina (Personally I think she can go down another tier, stuns shut her down hard and theres not much depth to her)
Blitzcrank
Twisted Fate
Udyr (I agree with this one surprisingly! he's made a good turnaround)
Tier 3 - Mid
Tristana (Bump this to top tier, she is an extremely viable ranged carry)
Sivir
Ashe
Janna
Malphite
Soraka
Taric (He's not total garbage but I think taric needs a buff, taking him down to tier 4)
Nasus (Bump nasus to top tier, move 5 boots, a small item that makes him amazing)
Singed
Sion
Anivia (Bump to top tier, amazing croud control, good damage, good survivability)
Ryze
Kassadin (Bump to top tier, silence wins games, survives very well, does good damage)
Nidalee
Tryndamere(Bump to top tier, A well played tyrn who knows how to use his ult properly.. well enough said)
Heimerdinger(demoted to tier 4, maybe 5 -- Defence is good, harassment is good.. aoe blind isn't all that wonderful, doesn't help much in team fights)
Tier 4 - Lacking
Dr. Mundo (agree Ex calling.. ouch)
Gangplank (Personally I'd throw him in mid or top tier, pirates that stack crit and don't get themselves killed are pretty broken)
Morgana (have to agree... her ult sucks.)
Karthus (Want to bump him up because i've seen amazing things done with him, but typically not that great... so here he stays.)
Tier 5 - Unusable
Evelynn (Love her to death but she has too many hard counters... here she stays)
Warwick... broken, Needs buff
Amumu (Bump to mid tier AOE stun wins fights)
Jax (Bump to mid tier)